Ion Exchange

Description

  • How it works
    • Contaminated solution passes over an ionic resin
    • A similarly charged benign ion replaces the contaminate ion in the water. The contaminate ion attaches to the resin
    • The benign ions go into the wastewater, while the contaminates remain trapped on the resin
    • When all the benign ions on the resin have gone into solution, the resin is 'spent'. Passing a concetrated solution containing these ions (acid or base) can regenerate the resin.
  • Removes impurities from:
    • Incoming water supply
    • Drag-in
    • Corrosion
    • Reduced or decomposed bath chemicals
    • Other sources too...

Advantages / Limitations

  • May not be practical for cyanide solutions (except gold cyanide)

For Incoming Water

  • Can reduce water use and wastewater generation by removing initial contaminates
  • Cleaner rinse may result in better quality of products

For Chemical Baths

  • Can reduce water use and wastewater generation
  • Increase plating rates
  • Decrease energy use

For Rinse Water

  • Can reduce water use and wastewater generation by keeping the water cleaner, longer
  • Cleaner rinse may result in better quality of products

Implementation Process

  • Determine operating conditions
    • For Incoming Water: Measure the quality of the incoming water supply and relate that to process cleanliness standards
    • For Chemical Baths: Identify the optimal process bath operating parameters (i.e. pH, ion concentration, etc.)
    • For Rinse Water: Determine optimal operating parameters
  • Investigate necessary equipment
    • Determine if the contaminates are cations, anions, or a combination of both
  • Determine cost effectiveness, including
    • chemical savings
    • disposal cost reduction
    • capital investment
    • energy cost
    • labor cost
    • resin replacement
  • Purchase and install equipment
  • Train and monitor employees – give incentives for superior performance

Resources

  • Cushnie, George C. Jr. Pollution Prevention and Control Technology for Plating Operations. National Center for Manufacturing Sciences, Ann Arbor, MI, 1994.

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